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    alice li

    3 years ago

    Protective piperidone can be used for synthesis and transformation reactions that have attracted much attention, including Knoevenagel reaction, heterogeneous Diels-Alder reaction, and the formation of N-(4-piperidyl) hydroxyindole. The raw material for synthesis of GABA analogues by direct Barbier- type addition reaction of alkyl phosphonate.

    “N-Benzyloxycarbonyl-4-piperidone
    1-benzyloxycarbonyl-piperidin-4-one
    1-carbobenzyloxy-4-piperidone
    1-Cbz-4-piperidinone
    Benzyl 4-oxo-1-piperidinecarboxylate
    1-Piperidinecarboxylic acid, 4-oxo-, phenylmethyl ester
    1-(Benzyloxycarbonyl)-4-piperidinone
    1-Z-4-Piperidone
    4-Oxo-1-piperidinecarboxylic Acid Benzyl Ester
    1-Cbz-4-piperidone
    benzyl 4-oxopiperidine-1-carboxylate
    1-Cbz-piperidin-4-one
    1-Benzyloxycarbonyl-4-piperidine
    N-CBZ-4-piperidone
    1-Carbobenzoxy-4-piperidone
    4-oxo-piperidine-1-carboxylic acid benzyl ester
    MFCD00673144”

    “Chemical Properties
    Colourless Oil

    Uses
    Protected piperidinone that can undergo interesting synthetic transformations including the Knoevenagel reaction,1 hetero-Diels-Alder reactions,2 and reactions to form N-(4-piperidinyl)oxindoles.

    General Description
    1-Z-4-Piperidone is the starting material in biheteroaromatic diphosphine oxides-catalyzed stereoselective direct aldol condensation reactions.

    Product Name 1-(Benzyloxycarbonyl)-4-piperidinone
    CAS NO. 19099-93-5
    EINECS 606-227-7
    Meltling Point 38-41°C
    Boiling Point 384.1±42.0 °C at 760 mmHg
    Flashing Point 186.1±27.9 °C
    Molecular Formula C13H15NO3
    Molecular Weight 233.263
    Purity 99%
    Density 1.2±0.1 g/cm3
    PSA 46.61
    LogP 1
    Refractive Index 1.56
    Vapour pressure 0.0±0.9 mmHg at 25°C
    Appearance White crystalline powder / White to pale yellow Solid or Lliquid
    HS Code 2933399090
    Shelf Life: 2years
    Storage Sealed in dry,2-8°C
    Stability “stable at room temperature and pressure
    Materials to Avoid: Oxides”
    Solubility Chloroform, Dichloromethane, Ethyl Acetate, Methanol

    https://www.whhoyan.com/products/pmk-glycidate-cas-28578-16-7.html

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alice li
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Hongyan Pharmaceutical Technology (Wuhan) Co., Ltd.

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